The Gavin and Stacey actor announced his departure from the CBS series last year, after around eight years in the hot seat.
As he gears up for his final episodes, it seems as though the 44-year-old has still got some surprises up his sleeve, including a segment with the Skims boss, 42.
The pair were spotted laughing together as they stopped off to pick up snacks in Malibu this week, with a camera crew following their every move.
In new pictures, they could be seen perusing the aisles of a petrol station, while the mom-of-four took the opportunity to try on hats.
Kim looked chic in a grey vest and ripped dark jeans, coupled with a pair of black heels and an extremely long ponytail.
James opted for a black polo top and jeans for the day, finishing the low-key outfit off with Gucci trainers.
They were seen giggling together before jumping into a Rolls Royce, presumably to continue filming for the upcoming episode.
While no further details have been shared about the clip, we’re hoping Kim managed to belt out a few lyrics to her infamous – and pretty damn catchy – hit, Jam (Turn It Up).
James has helmed the Late Late Show since 2015, but left viewers shocked when he confirmed that he would be stepping down from the Late Late Show this year.
Plans for his finale have now been confirmed, with the episode airing on April 27 – including an appearance from Tom Cruise.
The Cats actor previously opened up about what led to his decision and revealed that his children, Carey, Charlotte and Max, were the catalyst.
‘Look it’s not easy in any way to walk away from something that is so… I mean I’ll never work in a better environment than the one I work in now,’ he said on the Drew Barrymore Show.
‘Nothing about leaving the show was to do with not enjoying it. I love it, but the truth is it became a very easy decision because I always knew it was an adventure and I never ever considered it to be the final destination.’
He recalled: ‘I was filming on a Sunday and I came downstairs, it was about 6am and my son, who was 10 at the time, was sat on the stairs and he said, “Are you working today?” and I said, “I am,” and he said, “I thought, well it’s Sunday,” and I said, “I know buddy but this schedule’s just all over the place. We just got to get it done because we only have a tiny amount of time before we have to go back and do the show,” and his face just kind of dropped.
‘I got in the car and I called my wife Jules and I said, “I’ve realized, best case scenario we have six more summers where Max is like, even remotely wants to be around us and I cannot waste another one”.
‘So, really the choice was to go, “Well if I really want to do this other work, that cannot be at the expense of our children, our family,” and that is really all it comes down to.
‘I will be a mess on that last show. I will cry my eyes out but I will know at my core that the best thing for me and the best thing for us as a family is to put down some roots in London, and it feels absolutely right in every single way.’
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